1. three.
(1)
all 5 carbons line up linearly.
(2)
one carbon is center and other four sround it.(the center one connected with 4
carbons)
(3)
four carbons form linear and the other bond with the second/third one.
1)
The are three isomers of the hydrocarbon containing five carbons and
twelve hydrogens. The first is a
continuous chain of five carbons. The
first is connected to the second. The
second is connected to the first and third.
The third is connected to the second and fourth etc. Three hydrogens are bonded to each of the
end carbons and two hydrogens are bonded to each of the three remaining
carbons. The second isomer consists of
four carbons in a row with a fifth carbon bonded to the second carbon in the
chain. The second carbon also has one
hydrogen bonded to it. The two end
carbons and the one bonded to the second carbon each has three hydrogens. The remaining two are bonded to two
hydrogens each. The third isomer
consists of a central carbon bonded to four other carbons. The central carbon is bonded to no
hydrogens. Each of the other four is
bonded to four hydrogens.
Carbon attached to nitrogen would come
somewhere between carbon-carbon and carbon-oxygen, but probably closer to
carbon-oxygen. Because the
electronegativity of carbon nitrogen is quite high. THe difference in electronegativity causes dipole moments between
atoms. THe higher the electronegativity
the more drastic the dipole moments. In
a sense the longer an atom spends around the negatively charged nucleus the longer
the dipole moments. Therefore nitrogen
which has a high electronegativity would spend a lot of time around the nucleus
which would cause a long dipole moment, whereas carbon is not that
electronegative and therefore it would not spend quite as much time around the
nucleus.
2)the signal would come at about 40 ppm
because the electronegativity of nitrogen is less than that of oxygen which
gives a signal at 50 ppm and the electronegativity of nitrogen is much greater
than that of carbon which gives a signal at 15 ppm
2)
The ppm values for silicon bonded to carbon, carbon bonded to carbon,
and oxygen bonded to carbon were plotted on a graph with their respective
electronegativities. These three points
were connected with a smooth, curved line to produce a graph. This graph was then used with nitrogen's
electronegativity to estimate what the ppm value for nitrogen bonded to carbon
would be. The result suggested that a nitrogen
bonded to a carbon would have a ppm value near 27.5.
3)
Knowing both the empirical formula and the mass to charge ratio of the
charged cation (taken to be the molecular mass) the molecular formula can be
determined by dividing the molecular mass by the total mass of the empirical
formula. This result gives the factor
that the subscripts that the empirical formula must be multiplied by to yield
the molecular formula. In this case,
the factor was 4, and the resulting molecular formula was determined to have
four carbons and eight oxygens. This
was choice "C."