Schedule

Weekly Web Work #7:a

Lewis Dot Structures

The due date for this assignment had been extended to Friday, February 28, 2003 at NOON.
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The purpose of this week's assignment is to practice drawing Lewis dot structures.

Acetic acid, CH3COOH, is the component of vinegar that gives it its odor and taste. In order to draw the Lewis structure of acetic acid, you need to determine the number of valence electrons. Carbon has 4, oxygen has 6, and hydrogen has 1 valence electron. So, two carbon atoms times 4 electrons, plus two oxygen atoms times 6 electrons, plus four hydrogen atoms times 1 valence electron equals 24 valence electrons. 2(4)+2(6)+4(1)=24 valence electrons.

Look at the Lewis structure of acetic acid. Do you see 24 valence electrons? Remember each dash represents two electrons and each lone pair is two electrons.

There are 6 single bonds and one double bond in this structure and two lone pairs of electrons on each oxygen.

acetic acid

1. Determine the number of valence electrons for NH2CHCHOH by looking only at the formula.
2. Look at the structure on the left. Do all of the atoms have an octet (or a duet in the case of hydrogen)? If not, you need to add lone pairs to satisfy each atom. Explain where you would put lone pairs.

NH2CHCHOH

Chloroform, CHCl3, was an early anesthetic. Let's draw a Lewis structure for chloroform. First, determine the number of valence electrons. The next step is to write carbon as the central atom. Now, place hydrogen and chlorine atoms around the carbon. Draw a bond between carbon and each surrounding atom. Place lone pairs of electrons around any atom still needing an octet. (Remember, 2 electrons are all hydrogen needs to be satisfied.)

Examine your initial attempt to draw the Lewis structure of chloroform. Does every atom have an octet? Does the total number of electrons in your Lewis structure match the number of valence electrons actually available? If yes, cool. If not, do what all chemists do and rework your structure. Remember, drawing Lewis structures correctly involves a trial and error process.

3. How many valence electrons does chloroform have?
4. How many single bonds does chloroform have?
5. How many double bonds?
6. How many lone pairs of electrons?

Use the process above (determine the number of valence electrons, put carbon as the central atom, etc.) to draw the Lewis structure for carbon dioxide, CO2. When finished check the total number of electrons and make sure each atom has an octet.
7. How many valence electrons does carbon dioxide have?
8. Describe your Lewis dot structure. Include the number of single, double, or triple bonds and the location of any lone pairs.
 

Draw the Lewis dot structure for carbon disulfide, CS2, using the same strategy as before.
9. How many valence electrons does carbon disulfide have?
10. Describe your Lewis dot structure. Include the number of single, double, or triple bonds and the location of any lone pairs.
 
11. How is your structure for CS2 similar to your structure for CO2? Why could this be?
 

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