Lesson 8



Name:ETP Section:t3 Start Time:22:31:50 Instructor:pattersonet Course:421




1. The Helmholtz Free Energy F is defined by F = U - ts. Briefly, in words, what is the Helmholtz Free Energy, and why do you suppose it is not defined as F = U + ts instead?

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2. The average pressure on a system can be written in two terms, sometimes referred to as "energy pressure" and "entropy pressure." What are these terms, why are there two terms, and what's the importance (significance) of each term? Explain in your own words, with your explanation as physical as possible (i.e., think about a real system).

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3. Consider a system S in thermal contact with a reservoir R. The volume of the system is held constant. Which of the following is true?

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a) The system tries to have minimum energy and minimum entropy.
b) The free energy of the system is a maximum.
c) The free energy of the system is a minimum.
d) The system cannot depart from its equilibrium configuration because the volume is held constant.

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