WWW #6


Ions and Ionic Compounds

 

This is an archival version of the web assignment. It is after the due date, so the assignment can no longer be submitted.


The purpose of this assignment is to practice predicting ion charges and to practice writing chemical formulas for ionic compounds.

Note: The goal is to get you thinking about and working on this material. You are expected to utilize your text and the information within the assignment to figure out the answers to the questions.


The electron configurations of the noble gases are extremely stable. When an atom undergoes a chemical change to become an ion, the atom will gain or lose electrons until it is isoelectronic (has the same electron configuration) with the nearest noble gas. Metals tend to lose electrons and form positively charged ions called cations. Non-metals tend to gain electrons and form negatively charged ions called anions.

For example, sodium metal, Na, [Ne]3s1, loses one electron to form the Na+ ion which is isoelectronic with neon. (All the alkali metals have one valence electron and form 1+ cations.) Chlorine, [Ne]3s23p5, gains one electron to form the Cl ion which is isoelectronic with argon. (All of the halogens have 7 valence electrons and form 1- anions.)

Ionic compounds are composed of metal cation(s) and non-metal anion(s) and have a net charge of zero. Sodium chloride, NaCl, is composed of Na+ and Cl in a one to one ratio which gives the formula zero charge. When writing the formula for an ionic compound, the symbol for the cation is written first.


The following questions are designed to help you become proficient at predicting ions and writing formulas of ionic compounds. You may need to look at section 2.6 (pages 69-72) and section 3.2 (pages 88-95) in your textbook.

1. Predict the formula of the compound formed when lithium and fluorine react. Compare this formula to sodium chloride. Why are they similar?
 
   
2. What ion will magnesium form?
   
3. What ion will oxygen form?
   
4. What ion will aluminum form?
   
5. What ion will phosphorus form?

When writing the formula for ionic compounds, the total positive charge from the cations plus the total negative charge from the anions must add up to zero for the formula to have a zero net charge. When writing formulas for an alkali metal reacting with a halogen, the ratio of ions is one to one. Remember our example of NaCl above? NaCl is composed of Na+ and Cl ions. So 1(1+) + 1(1-) = 0

What about the compound that forms when calcium reacts with bromine? Calcium forms the 2+ ion, Ca2+, because it needs to lose 2 electrons to be isoelectronic with argon. Bromine forms the 1- ion, Br. The formula for calcium bromide is CaBr2. You need two bromide ions (-1 each) to balance the 2+ charge of the calcium ion.

6. Predict the formula of the compound formed when aluminum and chlorine react.
   
7. Explain the thought process you used to figure out the formula for aluminum chloride in question 6.
 
   
8. Predict the formula for the compound formed when rubidium and oxygen react.
   
9. Explain the thought process you used to figure out the formula for rubidium oxide in question 8.
 
   
 10.  Predict the formula for the compound formed when magnesium and phosphorus react.
   
11. Explain the thought process you used to figure out the formula for magnesium phosphide in question 10.
 
   
12. Consider the compound chromium (III) oxide. What is the formula of the compound? Hint: What are the charges on the chromium and oxygen ions?
 
   

 


 

This is an archival version of the web assignment. It is after the due date, so the assignment can no longer be submitted.


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